Oceanography 540--Marine Geological Processes--Autumn Quarter 2002
Overview of Marine Sedimentation
The term sediment refers to material composed of particles that have
settled to
bottom
of a liquid. Sediments are classified by the processes involved in
determining
their
physical and chemical character. Important distinguishing
characteristics
of sediments include:
- chemistry and mineralogy (reflecting origin of particles)
- grain size(s)
(reflecting energetics of transport, deposition)
- degree of compaction
and/or cementation (resulting from burial (physical) and
diagenesis (chemical)).
The source particles can be either preexisting rock (detrital sediments)
or prec
ipitates formed in the solution from which
they settle (chemical sediments).
Sources of marine sedimentary material
The material deposited in marine sediments has its origin on the
continents:
- rivers
- suspended load: 180 x 10 g/y
- dissolved load: 40 x 10 g/y (corrected for cyclic salt
component)
- wind
- atmospheric dust: 5 x 10 g/y
Within the suspended load, the materials are those that make up
the continents,
particularly those that are resistant to weathering or dissolve
incongruently, f
or example:
Eq 13-2:
These include quartz,
feldspar, and clay minerals such as kaolinite and montmorillonite.
These
clay minerals are products of
chemical weathering of primary igneous materials and typically very
fine-grained
.
Transport of Sediments
Physical processes dominate at ocean
margins, where they transfer particles eroded from the land to the
sea floor.
Active sedimentation
processes (where the sediment modifies the properties and
behavior of the suspension) include mass wasting and density
currents. Such deposition tends to mask other sedimentary processes.
The giant landslides surrounding the Hawaiian islands and the abyssal
plains of the Atlantic are striking deep-sea examples of active
sedimentation. Because active sedimentation depends on gravitational
energy, it does not extend seaward of the trenches along convergent
plate boundaries (but can affect the entire ocean basin off passive
margins).
Passive
sedimentationprocesses are those in which the sediment is
carried by but does not modify the normal thermohaline circulation.
Examples:
- Hemipelagic sedimentation, where it appears that fine
sediment moves along isopycnal surfaces high in the water column.
This process is poorly understood (for example, the role of
internal waves in resuspending sediment, the role of squirts and
jets in transporting sediment offshore and the role of biota in
sediment deposition have yet to be quantified). Hemipelagic
sedimentation produces a fringe of terrigenous (land-derived)
deposits up to a few hundred kilometers wide around land masses.
These deposits are draped uniformly over the sea floor
topography
- "Drift" deposition along the path of bottom currents.
Prominent in the high latitude North Atlantic along the flanks or
ridges. Sediment in transit to drift deposits creates a
near-bottom "nepheloid layer." Paleoceanography, 9
(6), (December 1994) has a dozen papers on drift deposits.
- Eolian (wind transported) sedimentation. Prominent
where major wind systems cross semi-arid source areas (ephemeral
lakes) or active ash-generating volcanoes. Prominent in the North
Pacific (Figure MS-1), North Atlantic and Arabian Sea
Figure MS-1. Quartz concentration in North Pacific sediments
(carbonate-free basis) showing effects of eolian transport in
westerlies and northeast trades.
- Ice rafting. Restricted to high latitudes, but can
carry coarse particles into the subarctic gyres, far from
land.
Sediments formed by physical processes have distinctive acoustic
signatures of military interest. Hence they have been much studied
during the past 50 years.
"Passive" sediments record the history of deep currents,
volcanism, aridity, wind trajectories, and iceberg abundances and
trajectories. Drift deposits, which can accumulate at hundreds of
meters per million years, yield some of the highest resolution
paleoceanographic records.
Biological processes dominate
sediment formation in areas of high productivity that receive little
terrigenous material. The equatorial Pacific and Southern Ocean are
examples.
Riverine dissolved material is distributed by ocean circulation
and mixin
g. The
principal pathway for particle production is primary production by a
variety of phytoplankton and zooplankton. Inorganic debris from dead
organisms becomes the
source for underlying sediment oozes. Most of this material is either
calcium carbonate or amorphous silica:
CaCO
- foraminiferal ooze
- organism: forams, a protozoan
most common source is genus
Globigerina
- mineral form: calcite
- coccolith ooze
- organism: algae coccolithophoridae
- mineral form: calcite
- pteropod ooze
- organism: planktonic molluscs
- mineral form: aragonite
SiO
- diatom ooze
- organism: algal diatoms
- mineral form: opal
- radiolarian ooze
- organism: radiolaria (protozoans)
- mineral form: opal
(The images are local copies from the WWW server at NGDC, National Geophysical Data
Center)
Benthic organisms also modify the historical record by actively
mixing ("bioturbating") the most recently deposited sediments.
Bioturbation, which is addressed later in the course, is
effectively a low-pass filter that supresses or eliminates records of
events that create layers of sediment thinner than the depth of
mixing. Rapidly deposited or anoxic sediments provide the only
deep-sea records capable of resolving events shorter than about a
millennium.
Chemical processes dominate
sedimentation only in deep, low productivity areas shielded from
terrigenous material. Precipitates from hydrothermal solutions
emanating from mid-ocean ridges are prominent along the flanks of the
East Pacific Rise in the South Pacific. Authigenic deposits
(formed by the very slow precipitation of oxyhydroxides and
silicates? from normal seawater) form distinctive sediments in the
central South Pacific as well as ferromanganese nodules (Figure MS-2)
and crusts on any surfaces where other sediments are absent or
accumulating extremely slowly.
Figure MS-2. Deep sea ferromanganese nodules on the floor of the
South Pacific Ocean (individual nodules are 5-10 cm diameter).
Distribution of Sediments
The physical processes affecting sediment distribution are reflected in
this map of sediment thickness:
Figure 13-3, from NOAA/NGDC, additional information is available concerning the
underlying database
Distribution of Recent (Surface) Sediments
The global distribution of surface sediment types is shown here:
Figure 13-4, from (2)
Except for areas near to the continents, which are dominated by hemipelagic contiental margin sediments and muds (and at high latitudes, glacial marine sediments), the predominant sediments in the deep ocean are biogenic oozes
and/or fine-grained clays.
The distribution of biogenic sediments responds to oceanic conditions in three ways:
- controls on primary productivity, especially those related to the intensity of upwelling
- The particle compositions exhibits increasing silica/carbonate ratio as
upwelling rate increases; there are also regional effects (temperature, light) on species
distributions
- corrosiveness of deep ocean waters to (settling particles and) surficial sediments
- Waters at all depths are undersaturated with respect to solid amorphous silica;
the driving force for dissolution decreases as deep water ages and develops higher dissolved silica concentration. (Because waters at all depths are undersaturated,
organisms must spend energy to precipitate amorphous silica.). The
siutation is more involved for calcium carbonate, with surface waters supersaturated
and deep waters undersaturated.
- topography
- Most of the dissolution of biogenic debris occurs at seafloor. Thus the topography influences the temperature and pressure conditions under which dissolution occurs.
We can illustrate the interaction of these three factors in generating a vertical sequence of sediment types lying on basement rock created on the East Pacific Rise somewhat south of the equator.
Figure 13-5, from (20)
Near to the ridge at which the basement rock is created, metalliferous
sediment (of hydrothermal origin) dominates the supply of material. Once away from this source of sediment,
carbonate material raining from above accumulates.
As the plate subsides, the dissolution of carbonate increases such that this material
is no longer preserved and only residual clay
material accumulates (at a much lower sedimentation rate). As the site passes
beneath the equator, the rate of supply of biogenic silica exceeds the rate of
dissolution and it accumulates. Further north beyond the equatorial band of productivity, red clay dominates again.
Stratigraphy
Sediments place events in time. Their study from this perspective is termed stratigraphy:
age relations of rock strata (layers). The objectives of stratigraphic studies are to
- establish markers of a sequence of events and thus relative ages of events,
- correlate these markers of events either regionally or globally, and,
- assign absolute ages (the basis of
these age assignments is radiometric dating of materials) or a chronology to these events.
The markers first employed were the skeleta of organisms preserved in rocks and so the description
of geological time is closely linked to the evolution of the plant and animal kingdoms.
Earth's history is divided into ages:
Figures 13-6ab
In ocean sediments, the Cenozoic and Mesozoic ages are represented. These ages can be further divided into
periods and epochs and stages:
Figure 13-7
Figure 13-8
(Figures 13-6, 7 and 8 courtesy of the University of California at Berkeley Museum of Paleontology,
their copyright notice. Their
web server offers an extensive
discussion of geological time in relation to evolution of the species.)
In establishing time scales for ocean sediments, stratigraphic correlations can be made in a number of ways:
- lithostratigraphy
- boundaries between rocks of different type or character (variant: seismic stratigraphy
recognizing these boundaries from seismic reflection profiles)
- biostratigraphy
- based on fossil content (presence, absence of particular indicator
species)
- chronostratigraphy
- based on ages of materials as established by radiometric methods
- magnetostratigraphy
- based on magnetic reversals recorded in sediments
- stable isotope stratigraphy
- based on oxygen isotopic composition of carbonate material, a signal dominated by global state of ice
storage on the continents during glacial times
For study of ocean sediments the most important tools are biostratigraphy
(applied throughout the Mesozoic and Cenozoic), magnetostratigraphy (important for the late Cenozoic sediments (past several My)), and oxygen
isotope stratigraphy (for Pleistocene sediments, last 1.8 My)
Indicators of Changes in Ocean Conditions
Our interest in Pleistocene sediments is derived from the record of climate change they
contain. There are two important classes of signals:
- Deposition Rates
- Signals indicating the extent to which material is deposited and preserved. These include
absolute
rates of net deposition and indices of changing proportions of materials (e.g., Si
vs. C, specific species)
- Chemical Signatures
- Signals involving properties of sedimentary materials which reflect conditions of original
deposition, either directly or as a proxy for some other property. Some examples are oxygen isotopic composition reflecting ice storage on
the continents (and to a lesser extent temperature of deposition); Sr/Ca reflecting the temperature of deposition (and to a lesser extent upwelling), and Cd/Ca
reflecting upwelling.
Background Information on Sediment Classification
Summarizing the classification of sedimentary rocks:
Figure 13-1
Figure
13-2, from the Geology 202 Pages at University of British Columbia
Chemical Sediments, both allochems (precipitates formed in basin
of deposition) and precipitates (precipitates formed in deposit itself)
| Limestone | Dolomite | Iron
formation | Evaporite | Chert | Organics | Phosphate
|
---|
Chemical
Composition | CaCO3 | CaMg(CO3)2 | Fe silicate oxide carbonate | NaCl, CaSO4 | SiO2 | C | Ca3(PO4)2
|
---|
Minerals | calcite, aragonite | dolomite | hematite,
limonite, siderite | halite, gypsum, anhydrite, other salts | opal,
chalcedony, quartz | coal, oil, gas | apatite
|
---|
Marine sediments are further classified:
- median grain size <5µm: pelagic deposit (clays and oozes)
- biogenic component <30%: calcareous or siliceous clay
- biogenic component >30%
- calcareous component dominant
- carbonate component <67%: marl ooze
- otherwise: chalk ooze
- siliceous component dominant: diatom or radiolarian ooze
- median grain size >5µm: hemipelagic deposit (muds)
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